Highly stable carbon coated Mg2Si intermetallic nanoparticles for lithium-ion battery anode
| Autor: | Andebet Gedamu Tamirat, Yao Liu, Long Fan, Mengyan Hou, Yonggang Wang, Yunhe Sun, Duan Bin, Yongyao Xia |
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| Rok vydání: | 2018 |
| Předmět: |
Materials science
Silicon Renewable Energy Sustainability and the Environment Intermetallic Energy Engineering and Power Technology Nanoparticle chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences Lithium-ion battery 0104 chemical sciences Anode Chemical engineering chemistry Electrode Lithium Electrical and Electronic Engineering Physical and Theoretical Chemistry 0210 nano-technology |
| Zdroj: | Journal of Power Sources. 384:10-17 |
| ISSN: | 0378-7753 |
| DOI: | 10.1016/j.jpowsour.2018.02.008 |
| Popis: | Silicon is an ideal candidate anode material for Li-ion batteries (LIBs). However, it suffers from rapid capacity fading due to large volume expansion upon lithium insertion. Herein, we design and fabricate highly stable carbon coated porous Mg2Si intermetallic anode material using facile mechano-thermal technique followed by carbon coating using thermal vapour deposition (TVD), toluene as carbon source. The electrode exhibits an excellent first reversible capacity of 726 mAh g−1 at a rate of 100 mA g−1. More importantly, the electrode demonstrates high rate capability (380 mAh g−1 at high rate of 2 A g−1) as well as high cycle stability, with capacity retentions of 65% over 500 cycles. These improvements are attributable to both Mg supporting medium and the uniform carbon coating, which can effectively increase the conductivity and electronic contact of the active material and protects large volume alterations during the electrochemical cycling process. |
| Databáze: | OpenAIRE |
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