Removal of rare earth elements from a U/RE ingot via a reaction with UCl3

Autor:	Seungwoo Paek, Junhyuk Jang, Gha-Young Kim, Sung-Jai Lee, Dalsung Yoon
Rok vydání:	2019
Předmět:	Materials science Health Toxicology and Mutagenesis Metallurgy Rare earth Public Health Environmental and Occupational Health chemistry.chemical_element Pyroprocessing Uranium Pollution Chloride Analytical Chemistry Transuranic waste Nuclear Energy and Engineering chemistry medicine Radiology Nuclear Medicine and imaging Molten salt Chemical equilibrium Ingot Spectroscopy medicine.drug
Zdroj:	Journal of Radioanalytical and Nuclear Chemistry. 322:495-502
ISSN:	1588-2780 0236-5731
Popis:	A chemical equilibrium experiment was conducted to remove rare earth (RE) elements from a U/RE ingot using UCl3 as an oxidant. Upon analysis, the RE and uranium in the prepared U/RE ingot formed discrete matrixes and were not well mixed. The reaction with UCl3 resulted in the complete removal of the RE matrix from the U/RE specimen, and an increased concentration of RE chloride and a drastically reduced concentration of UCl3 in the LiCl–KCl molten salt. The results of this study will be used to improve the process for transuranic waste treatment in pyroprocessing.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bd180bcec7b6ca6acdaef07b296b8173 https://doi.org/10.1007/s10967-019-06716-1 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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