Onium salts of sulfur-containing oxyanions resulting from reaction of sulfur(IV) oxide with aqueous solutions of 1,2-diamines and morpholine

Autor: Vyacheslav N. Baumer, R. E. Khoma, A. V. Mazepa, A. A. Ennan, T. V. Koksharova, A. N. Puzan, Vladimir O. Gelmboldt
Rok vydání: 2017
Předmět:
Zdroj: Russian Journal of Inorganic Chemistry. 62:736-745
ISSN: 1531-8613
0036-0236
DOI: 10.1134/s0036023617060109
Popis: Reaction products have been isolated from SO2–L–H2O–О2 systems (L = ethylenediamine, N,N,N′,N′-tetramethylethylenediamine, piperazine, and morpholine) as onium salts [H3NCH2CH2NH3]SO4, [(CH3)2NHCH2CH2NH(CH3)2]SO4, [(CH3)2NHCH2CH2NH(CH3)2]S2O6 ⋅ H2O, [C4H8N2H4]SO3 ⋅ H2O, [C4H8N2H4]S2O6, [C4H8N2H4]SO4 ⋅ H2O, [O(C2H4)2NH2]2SO4 ⋅ H2O. The prepared compounds have been characterized by X-ray diffraction analysis, X-ray powder diffraction, IR and mass spectroscopy.
Databáze: OpenAIRE