Branched Polyamines Functionalized with Proposed Reaction Pathways Based on 1H-NMR, Atomic Absorption and IR Spectroscopies

Autor:	Rosario Merino-García, Vicente Cervantes-Mejía, Elizabeth Baca-Solis, Yasmi Reyes-Ortega, Jesús Cruz-Gatica, Judith Caballero-Jiménez, Gabriela Moreno-Martínez
Rok vydání:	2014
Předmět:	Psychiatry and Mental health chemistry.chemical_compound chemistry Salicylaldehyde Polymer chemistry Imine Proton NMR Infrared spectroscopy Organic chemistry Ethylenediamine Amine gas treating Mass spectrometry Propanamide
Zdroj:	American Journal of Analytical Chemistry. :1090-1101
ISSN:	2156-8278 2156-8251
DOI:	10.4236/ajac.2014.516116
Popis:	Three novel branched polyamines N,N,N’,N’-tetrakis-[3((pyridine-2-methyl)-amine) propyl]-1,4- butanediamine (1), N,N,N’,N’-tetrakis-[N-((2-methylpyridine)ethyl)propanamide]ethylenediamine (2) and N,N,N’,N’-tetrakis-[3((2-hidroxibenziliden)-amine)propyl]-1,4-butanediamine (3), were synthesized starting from 2-pyridinecarboxaldeyde with DAB-Am-4 for 1, PAMAM G0 for 2 and from salicylaldehyde with DAB-Am-4 for 3. The pathway reactions have been proposed by 1H-NMR, IR and Atomic Absorption Spectroscopy. The optimal reaction time was set by IR spectroscopy following aldehyde peak modification. 1 and 2 were obtained as both hydrochlorides and as free amines and 3 only as free imine. These polyamines were characterized by UV-Vis, IR, 1H-NMR and 13C-NMR and Mass Spectrometry.
Databáze:	OpenAIRE
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