Stereochimie du motif de coordination dans les complexes a ligands mixtes du type MII(bipy)(H2O)2AB4 (MII = NiII ou CuII; AB42− = SO42− ou BeF42−) bipy: 2,2′ bipyridine

Autor:	C. Avinens, Nguyen Dinh Phung, Jean-Claude Tedenac, Maurice Maurin
Rok vydání:	1976
Předmět:	Nickel Bipyridine chemistry.chemical_compound Crystallography Polymers and Plastics chemistry Stereochemistry Materials Chemistry chemistry.chemical_element Crystal structure Copper
Zdroj:	Journal of Inorganic and Nuclear Chemistry. 38:85-89
ISSN:	0022-1902
DOI:	10.1016/0022-1902(76)80055-3
Popis:	The authors have studied three complexes of 2,2′ bipyridine: Ni(C10H8N2)(H2O)2SO4∗, Cu(C10H8N2)-(H2O) 2SO4∗∗, Cu(C10H8N2)(H2O)2BeF4. The crystal structure has been solved for two of them (∗ and ∗∗). Moreover their electronic, ESR and i.r. spectra are reported. By correlating these data the authors describe without ambiguity the crystal structure and the local molecular environment for copper (II) and nickel (II).
Databáze:	OpenAIRE
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