ChemInform Abstract: Synthesis and Reactivity of a Nickel(II) Complex with a Macrocycle Containing a Peripheral Hydroxyl Group

Autor:	Daryle H. Busch, Harrell E. Tweedy, Neil A. Stephenson
Rok vydání:	1990
Předmět:	Nickel Template reaction chemistry Group (periodic table) Closure (topology) chemistry.chemical_element Reactivity (chemistry) General Medicine Macrocyclic ligand Medicinal chemistry
Zdroj:	ChemInform. 21
ISSN:	0931-7597
DOI:	10.1002/chin.199010264
Popis:	The neutral nickel(II) complex of an anionic macrocyclic ligand, [Ni(Ac 2 Me 2 (OH) [15]tetraenato-κ 4 N)], is formed by a template reaction involving the closure of [3,3'-(ethylenebis(iminomethylidene))bis(2,4-pentanedionato)]nickel(II) with 1,3-diamino-2-propanol. The uncoordinated hydroxyl group on the macrocyclic ligand reacts smoothly with acylating agents
Databáze:	OpenAIRE
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