Synthesis and Characterization of Copper Complexes with a Tridentate Nitrogen-Donor Ligand: An Integrated Research Experiment for Undergraduate Students

Autor:	Kayode D. Oshin, Margaret E. Mraz, Annie R. Cavalier, Ashley S. Holderread, Jennifer R. Connell, Tomislav Pintauer, Katherine A. Bussey
Rok vydání:	2015
Předmět:	Reaction mechanism Chemistry Metalation Ligand Nanotechnology General Chemistry Nuclear magnetic resonance spectroscopy Combinatorial chemistry Education Characterization (materials science) chemistry.chemical_compound Undergraduate research Organic synthesis Cyclic voltammetry
Zdroj:	Journal of Chemical Education. 92:2140-2145
ISSN:	1938-1328 0021-9584
DOI:	10.1021/acs.jchemed.5b00175
Popis:	An integrated laboratory experiment applying concepts and techniques developed in organic chemistry, inorganic chemistry, and instrumental analysis is presented for use by students interested in undergraduate research. The experiment incorporates some advanced laboratory practices such as multistep organic synthesis and purification, detailed reaction mechanism, air-sensitive metalation techniques, variable-temperature NMR experiments, cyclic voltammetry, and single crystal X-ray crystallography. Subsequently, students are presented with an experience that mirrors fundamental inorganic chemistry research practices found in laboratories throughout the world.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b99231cd7a1b69647bd0f438a502faea https://doi.org/10.1021/acs.jchemed.5b00175 Zobrazit plný text záznamu