Palladium-Catalyzed Carbonylative Esterification of Primary Alcohols with Aryl Chlorides through Dehydroxymethylative C–C Bond Cleavage

Autor:	Chul Ho Jun, Hyo Soon Park, Dong-Su Kim
Rok vydání:	2014
Předmět:	inorganic chemicals Primary (chemistry) Chemistry Aryl Decarbonylation chemistry.chemical_element General Chemistry Medicinal chemistry Catalysis chemistry.chemical_compound Alkoxy group Organic chemistry Bond cleavage Palladium
Zdroj:	ACS Catalysis. 5:397-401
ISSN:	2155-5435
DOI:	10.1021/cs501778q
Popis:	Aryl chlorides in the presence of Pd/C catalyst and NaF react with primary alcohols to form esters, arenes, and alkanes. In this reaction, aryl chlorides act as both oxidants and coupling partners, whereas alcohols serve as both carbonyl sources and alkoxy components of the ester products
Databáze:	OpenAIRE
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