Carbon-13 nuclear magnetic resonance spectra of isomeric oxaziridines. Effects of the nitrogen lone pair on carbon-13 chemical shifts

Autor:	Guy J. Jordan, Delanson R. Crist
Rok vydání:	1977
Předmět:	Nuclear magnetic resonance chemistry Chemical shift Carbon-13 chemistry.chemical_element General Materials Science General Chemistry Photochemistry Carbon Nitrogen Lone pair Spectral line
Zdroj:	Organic Magnetic Resonance. 9:322-324
ISSN:	1097-458X 0030-4921
DOI:	10.1002/mrc.1270090607
Popis:	The carbon-13 n.m.r. spectra of several oxaziridines were measured. Aliphatic and aromatic ipso carbon atoms trans to the lone pair of nitrogen in oxaziridines were shifted upfield by c. 9 ppm, and 3.4 ppm, respectively, in comparison with isomers of inverted configuration. The results suggest that the nitrogen lone pair is partially responsible for the observed upfield shifts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b8fa8239b3bdec03e5057099cb3dc2de https://doi.org/10.1002/mrc.1270090607 Zobrazit plný text záznamu Plný text