Ultrasonic phonon behavior near the pressure-induced cubic-to-orthorhombic transformation in PbF2

Autor: R.J. Sladek, M.H. Chao, D.S. Rimai
Rok vydání: 1980
Předmět:
Zdroj: Solid State Communications. 35:213-216
ISSN: 0038-1098
DOI: 10.1016/0038-1098(80)90482-2
Popis: Measurements have been made of the transit times τ of pulses of 30 MHz longitudinal and transverse ultrasonic waves in PbF2 at room temperature using hydrostatic pressures up to where the irreversible cubic-to-orthorthombic transformation occurs (near 4 kbar). Above 3 kbar 1/τ no longer increased linearly with pressure and exhibited some time dependence at fixed pressures before echo disappearance. The elastic stiffness moduli showed no significant softening before the transformation began. Length, mass density, and X-ray measurements on samples after they had been returned to 1 bar confirmed that milky white regions in them were orthorhombic but filled with defects.
Databáze: OpenAIRE