Chemical Nuclear Polarization of Biradicals Created by Photolysis of Cyclic Aliphatic Ketones in the Gas Phase

Autor:	K. M. Salikhova, P. A. Purtovb, A. A. Obynochnyia
Rok vydání:	2008
Předmět:	Cycloundecanone Chemistry Buffer gas Photodissociation Molecule Physical and Theoretical Chemistry Polarization (electrochemistry) Kinetic energy Photochemistry Gas phase
Zdroj:	Russian Journal of Physical Chemistry. 82:298-302
ISSN:	1531-863X 0036-0244
Popis:	Chemical nuclear polarization (CNP) of short-lived biradicals created in the photolysis of cyclic ketones in the gas phase with a buffer gas of CDCl3 molecules was studied theoretically and experimentally. The magnetoresonance and kinetic parameters were proposed for the biradicals. The experimental fact that the CNP of cycloundecanone in the gas phase and liquid was the strongest was confirmed by calculations. The computational results agree well with the experiment for both gas and liquid phases.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b89ec7617a2a052708ef7ae5fa52ee13 https://doi.org/10.1134/s0036024408020283 Zobrazit plný text záznamu Full text from SpringerLink