Synthesis and Stille Cross-Coupling Reactions of 2-(Tributylstannyl)- and 2,5-Bis(trimethylstannyl)tellurophene

Autor:	Daniel P. Sweat, Chad E. Stephens
Rok vydání:	2009
Předmět:	chemistry.chemical_classification Aryl Organic Chemistry Iodide chemistry.chemical_element Copper Medicinal chemistry Catalysis Coupling reaction Stille reaction chemistry.chemical_compound chemistry Organic chemistry Triphenylphosphine Palladium
Zdroj:	Synthesis. 2009:3214-3218
ISSN:	1437-210X 0039-7881
DOI:	10.1055/s-0029-1216958
Popis:	Herein, we describe the synthesis and Stille cross-coupling reactions of 2-(tributylstannyl)- and 2,5-bis(trimethylstannyl)tellurophene. The reactions were most optimal when using aryl iodides as coupling partners, and a mixed catalyst system consisting of tetrakis(triphenylphosphine)palladium(0) and copper(I) iodide, together with cesium fluoride as additive, in N,N-dimethylformamide. This is the first reported synthesis and use of stannylated tellurophenes for cross-coupling reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b7f8374a1f77b64843ee37497d4a8811 https://doi.org/10.1055/s-0029-1216958 Zobrazit plný text záznamu