Absorption edge parameters of the L III edge for compounds of Hg, Tl, Pb and Bi using EDXRF technique
| Autor: | Manoj Gupta, Amrit Singh, K.S. Kahlon, Gurinderjeet Singh, A.S. Dhaliwal |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Radiation
010308 nuclear & particles physics Chemistry Radioactive source Detector Analytical chemistry Edge (geometry) 010403 inorganic & nuclear chemistry 01 natural sciences 0104 chemical sciences Absorption edge Attenuation coefficient 0103 physical sciences Constant (mathematics) Effective atomic number |
| Zdroj: | Radiation Physics and Chemistry. 144:280-287 |
| ISSN: | 0969-806X |
| DOI: | 10.1016/j.radphyschem.2017.08.026 |
| Popis: | The measurement of Absorption edge parameters of the L III edge of pure elements Hg, Tl, Pb and Bi along with their compounds HgCl2, HgO, HgF2, TlCl, Tl2O3, PbCl2, PbF2, Pb3O4, BiF3, BiCl3 and Bi2O3 has been done using EDXRF technique. In the present measurements 241Am (59.54 keV) radioactive source of activity 100 mCi along with CANBERRA make cryo-cooled Si (Li) detector is used. The measured results are compared with theoretically calculated values from FFAST version 2.1 (Chantler et al., 2005) and shows good agreement with each other within experimental uncertainties within 3.5%. It is observed that the values of absorption edge parameters of the LIII edge depends slightly on the chemical environment and shows almost constant behaviour with effective atomic number ( Z eff ) |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect