Influence of oligomeric unsaturated polyketone on the vulcanization of elastomeric compositions in the presence of sulfenamide C
| Autor: | D. E. Babushkin, S. V. Semikolenov, V. D. Voronchihin, O. V. Sorochenko, D. P. Ivanov, Konstantin A. Dubkov |
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| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Sulfide 010405 organic chemistry Sulfenamide Vulcanization General Chemistry Nuclear magnetic resonance spectroscopy 010402 general chemistry Elastomer 01 natural sciences 0104 chemical sciences law.invention chemistry.chemical_compound chemistry law Polyketone Polymer chemistry Amine gas treating |
| Zdroj: | Russian Chemical Bulletin. 69:2171-2176 |
| ISSN: | 1573-9171 1066-5285 |
| DOI: | 10.1007/s11172-020-3018-x |
| Popis: | Effect of the oligomeric unsaturated polyketone (UPK) additive on the rheological properties, vulcanization, and structural characteristics of elastomeric compositions based on butadiene and nitrile-butadiene rubbers containing N-cyclohexyl-2-benzothiazolylsulfenamide (sulfenamide C) as vulcanizing accelerator is investigated. It was demonstrated using IR and NMR spectroscopy that sulfenamide C reacts with polyketone. A mechanism for such interaction, which includes the sequential addition of benzothiazyl sulfide and amine fragments to the oligomeric chain, was proposed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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