Synthesis of molybdenum and tungsten silylimido complexes. Structure of a five-coordinate bis(silylimido) complex

Autor:	Nancy M. Doherty, Joseph D. Lichtenhan, Susan C. Critchlow
Rok vydání:	1990
Předmět:	Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Molybdenum Inorganic chemistry X-ray crystallography Trimethylsilyl azide Molecule chemistry.chemical_element Crystal structure Physical and Theoretical Chemistry Tungsten
Zdroj:	Inorganic Chemistry. 29:439-442
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00328a019
Popis:	Molybdenum(IV) and tungsten(IV) mono(silylimido) compounds, M(NSiMe 3 )Cl 2 L 3 (M=Mo, L=PMe 3 , M=W, L=PMe 3 , PMePh 2 , have been prepared by the reaction of MCl 2 L 4 with trimethylsilyl azide. When M=W and L=PMePh 2 , the addition of a second equivalent of trimethylsilyl azide produces a tungsten(VI) bis(silylimido) compound, W-(NSiMe 3 ) 2 Cl 2 (PMePh 2 ) (4). X-ray structural determination indicates that 4 possesses a five-coordinate trigonal-bipyramidal structure
Databáze:	OpenAIRE
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