Hydrolysis of nitrilium derivatives of the closo-decaborate anion [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5)
| Autor: | N. T. Kuznetsov, A. Yu. Bykov, I. N. Polyakova, A. S. Kubasov, K. Yu. Zhizhin, G. A. Razgonyaeva, Andrey P. Zhdanov |
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| Rok vydání: | 2017 |
| Předmět: |
Chemistry
Materials Science (miscellaneous) Inorganic chemistry Crystal structure 010402 general chemistry 010403 inorganic & nuclear chemistry Alkali metal 01 natural sciences Medicinal chemistry 0104 chemical sciences Ion Inorganic Chemistry chemistry.chemical_compound Hydrolysis 13c nmr spectroscopy Physical and Theoretical Chemistry Nitrilium |
| Zdroj: | Russian Journal of Inorganic Chemistry. 62:468-475 |
| ISSN: | 1531-8613 0036-0236 |
| DOI: | 10.1134/s0036023617040210 |
| Popis: | Reaction of tetrabutylammonium salts of [2-B10H9(N≡CR)]– (R = CH3, C2H5, C(CH3)3, or C6H5) anions with water results in N-borylated iminols (Bu4N)[2-B10H9NH=C(OH)R], and in the presence of an alkali, corresponding N-substituted amides (Bu4N)2[2-B10H9NH-C(=O)R] are formed. The compounds obtained are identified by IR, ESI/MS, and 1H, 11B, and 13C NMR spectroscopy. The crystal structure of compound (Bu4N)[2-B10H9(Z-{NHC(OH)C2H5})] is studied by X-ray diffraction. |
| Databáze: | OpenAIRE |
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