Heteronuclear compounds of arsenic and antimony

Autor:	James E. Mauser
Rok vydání:	1982
Předmět:	inorganic chemicals Volatilisation integumentary system Metals and Alloys chemistry.chemical_element Condensed Matter Physics Copper Bismuth chemistry Copper extraction techniques Antimony Mechanics of Materials Environmental chemistry Smelting Materials Chemistry Arsenic Roasting
Zdroj:	Metallurgical Transactions B. 13:511-513
ISSN:	2379-0229 0360-2141
DOI:	10.1007/bf02667768
Popis:	Volatilization of secondary metals such as arsenic, antimony, and bismuth, during the smelting of copper ores, is important because of environmental and resource considerations. The Bureau of Mines, United States Department of the Interior, has been studying copper concentrate roasting in conjunction with the volatility of these minor constituents. Some unusual vaporization behavior initiated this supplemental paper which shows that when the mixed sulfides of arsenic and antimony are heated, the volatilization of arsenic is retarded and the volatilization of antimony increased. Mixed oxides of arsenic and antimony also exhibit exceptional volatilization behavior. These anomalous vaporization behaviors are attributed to the formation of heteronuclear compounds of arsenic and antimony, but the colligative properties of solutions may also be a factor.
Databáze:	OpenAIRE
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