Synthesis of 2,2,6,6-tetramethylquinuclidine

Autor:	E. S. Nikitskaya, V. S. Usovskaya, E. I. Levkoeva, M. V. Rubtsov, L. N. Yakhontov
Rok vydání:	1971
Předmět:	chemistry.chemical_compound Geminal Chemistry Organic Chemistry Organic chemistry Knoevenagel condensation Triacetonamine Quinuclidine
Zdroj:	Chemistry of Heterocyclic Compounds. 7:212-216
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00473091
Popis:	A method was developed for the synthesis of the first representative of the previously unreported quinuclidine derivatives with four geminal substituents in the α-positions with respect to nitrogen, viz., 2,2,6,6-tetramethylquinuclidine, from triacetonamine. Two variants were studied for building up the chain from two CH2 links in the γ-position of triacetonamine using the Reformatskii and Knoevenagel reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b08fc3b4d2045d52b98c85d47a62084c https://doi.org/10.1007/bf00473091 Zobrazit plný text záznamu Full text from SpringerLink