Autor:	David W. Thomas, John D. Spence, Amanda E. Hargrove, Hannah L. Crampton
Rok vydání:	2007
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Bergman cyclization Organic Chemistry Drug Discovery Photodissociation Substituent Alkyne Photochemistry Biochemistry Medicinal chemistry
Zdroj:	Tetrahedron Letters. 48:725-728
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2006.10.164
Popis:	Synthetic methodology to prepare porphyrinylethynyl enediynes has been developed. Compared to phenylethynyl derivatives, a bulky porphyrinic substituent on the alkyne significantly increases the thermal barrier toward Bergman cyclization and leads to multiple photolysis products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b02ccad4f0b1d76d818fdec5f03a0a11 https://doi.org/10.1016/j.tetlet.2006.10.164 Zobrazit plný text záznamu Full Text from ScienceDirect