An interlocked coordination cage based on aromatic amide ligands
| Autor: | Bo Pan, Chunmiao Ma, Jiajia Zhang, Yuyang Su, Dan Luo, Quan Gan |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Denticity
Ligand Hydrogen bond Stacking chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Crystallography chemistry.chemical_compound chemistry Coordination cage Amide Proton NMR 0210 nano-technology Palladium |
| Zdroj: | Chinese Chemical Letters. 32:1397-1399 |
| ISSN: | 1001-8417 |
| DOI: | 10.1016/j.cclet.2020.11.002 |
| Popis: | An interlocked M4L8 coordination cage was synthesized by coordination-driven self-assembly of palladium(II) ions with aromatic amide bidentate ligands. The reaction of the ligand and the metal at 2:1 ratio led to the monomeric M2L4 cage as the kinetic product, while the thermodynamic product M4L8 cage was obtained by prolongating the reaction. This conversion and the interlocked structure was clearly revealed by using 1H NMR, mass spectrometry and X-ray crystallography. The driving force of interlocking was mainly attributed to the interactions (hydrogen bonding, aromatic stacking and electrostatic interaction) arising from the aptitude of flexibility of the amide ligand. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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