Synthesis and structure of diorganyldiaryloxytelluranes with intramolecular Te ⋯ N coordination bonds

Autor:	Gopal K. Mehrotra, O. E. Kompan, Yu. T. Struchkov, Dmitry S. Yufit, A. G. Maslakov, I. D. Sadekov, Vladimir I. Minkin, A. A. Maksimenko
Rok vydání:	1988
Předmět:	chemistry.chemical_classification Aldimine Stereochemistry Organic Chemistry Crystal structure Biochemistry Inorganic Chemistry NMR spectra database Solvent Crystallography chemistry Intramolecular force X-ray crystallography Materials Chemistry Nitro Molecule Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 348:63-77
ISSN:	0022-328X
DOI:	10.1016/0022-328x(88)80340-1
Popis:	A wide series of diorganyldiaryloxytelluranes having an azomethine function in the position ortho to the tellurium atom have been synthesized by the reaction of diorganyldimethoxytelluranes with benzylidene- o -aminophenols. The X-ray structural investigation of the dimethylbis[2-(4-nitrobenzylideneimino)phenyloxy]tellurane indicates the presence of an intramolecular coordination bond Te ⋯ N. According to the dipole moment data and the 1 H, 125 Te, 14 N NMR spectra, in compounds VII, excluding those having nitro groups in the position para to the CHN bond, the Te ⋯ N coordination is retained in a non-polar solvent (benzene).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::af83a5d5de96b7afeebf41740f280152 https://doi.org/10.1016/0022-328x(88)80340-1 Zobrazit plný text záznamu