Complete1H and13C signal assignment of prenol-10 with 3D NMR spectroscopy
| Autor: | Maria Misiak, Ewa Ciepichal, Wiktor Koźmiński, Jacek Wójcik, Ewa Swiezewska, Maria Kwasiborska |
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| Rok vydání: | 2009 |
| Předmět: |
Chemical shift
Analytical chemistry High resolution General Chemistry Nuclear magnetic resonance spectroscopy Signal Prenol Interpretation (model theory) NMR spectra database chemistry.chemical_compound symbols.namesake Fourier transform chemistry symbols General Materials Science Statistical physics |
| Zdroj: | Magnetic Resonance in Chemistry. 47:825-829 |
| ISSN: | 0749-1581 |
| DOI: | 10.1002/mrc.2473 |
| Popis: | The complete assignment of 1H and 13C chemical shifts of natural abundance prenol-10 is reported for the first time. It was achieved using 3D NMR experiments, which were based on random sampling of the evolution time space followed by multidimensional Fourier transform. This approach makes it possible to acquire 3D NMR spectra in a reasonable time and preserves high resolution in indirectly detected dimensions. It is shown that the interpretation of 3D COSY–HMBC and 3D TOCSY–HSQC spectra is crucial in the structural analysis of prenol-10. Copyright © 2009 John Wiley & Sons, Ltd. |
| Databáze: | OpenAIRE |
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