Development of a new shape-memory polymer in the form of microspheres
| Autor: | Junxian Huang, Lijun Lai, Jihua Gao, Shaojun Chen, Heng Chen |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Materials science Mechanical Engineering Butyl acrylate 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Divinylbenzene 01 natural sciences 0104 chemical sciences Styrene Shape-memory polymer chemistry.chemical_compound chemistry Chemical engineering Mechanics of Materials Phase (matter) Digital Video Broadcasting General Materials Science Deformation (engineering) 0210 nano-technology |
| Zdroj: | Materials Letters. 225:24-27 |
| ISSN: | 0167-577X |
| DOI: | 10.1016/j.matlet.2018.04.066 |
| Popis: | A novel shape-memory polymer having microspherical structure was prepared with Styrene (St), butyl acrylate (BA) and divinylbenzene (DVB) as the crosslinkers. The results clearly show the formation of crosslinked poly(St-DVB-BA) polymeric microspheres with high content of DVB. Through the variation of DVB content, different microspheres are formed, each having two-phase separation structure consisting of BA soft phase and St hard phase respectively. Both the St hard phase and chemical-crosslinker provided stable netpoints for thermally induced shape-memory effects. Thus, the Poly(St-DVB-BA) microspheres show the capability of shape deformation, shape fixation and shape recovery. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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