Heat Capacity and the Thermodynamic Properties of Layered Perovskite-Like Oxides K2La2Ti3O10 and K2Nd2Ti3O10
Autor: | N. N. Smirnova, Alexey V. Markin, Anna M. Sankovich, Irina A. Zvereva |
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Rok vydání: | 2019 |
Předmět: |
Materials science
Enthalpy Analytical chemistry 02 engineering and technology Calorimetry Atmospheric temperature range 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Heat capacity 0104 chemical sciences Gibbs free energy symbols.namesake Differential scanning calorimetry symbols Physical and Theoretical Chemistry 0210 nano-technology Adiabatic process Perovskite (structure) |
Zdroj: | Russian Journal of Physical Chemistry A. 93:407-416 |
ISSN: | 1531-863X 0036-0244 |
Popis: | The heat capacity of perovskite-like layered titanates K2La2Ti3O10 and K2Nd2Ti3O10 is studied via precision adiabatic vacuum calorimetry in the temperature range of 7–350 K, and by differential scanning calorimetry in the range 350–670 K. Standard thermodynamic functions are calculated from experimental data on heat capacity in the temperature range of 9–670 K: enthalpy H(T) − H(9), entropy S(T) − S(9), and Gibbs function −[G(T) − G(9)]. |
Databáze: | OpenAIRE |
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