Ancillary Ligand-Controlled Selectivity for Metal or Cyclopentadienyl Ring Fluoroalkylation in Reactions of Fluoroalkyl Iodides with Cyclopentadienylrhodium Complexes

Autor:	Trang Le Husebo, and Louise M. Liable-Sands, Arnold L. Rheingold, Glenn P. A. Yap, Russell P. Hughes,† and
Rok vydání:	1997
Předmět:	Inorganic Chemistry Metal Primary (chemistry) Cyclopentadienyl complex Chemistry Ligand visual_art Organic Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Selectivity Ring (chemistry) Medicinal chemistry
Zdroj:	Organometallics. 16:5-7
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om960848p
Popis:	Reactions of [Rh(η5-C5H5)(CO)2] with isomeric primary and secondary fluoroalkyl iodides proceed by selective fluoroalkylation at the metal center to give [Rh(η5-C5H5)(CO)(RF)I], and treatment of th...
Databáze:	OpenAIRE
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