Preparation and Characterization of Storage and Emission Functional Material of Chlorine Anion: [Ca24Al28O64]4+ (Cl)3.80(O2)0.10

Autor:	Shao-bin Lin, Jianqiu Sun, Shen Ning, Quanxin Li, Chongfu Song
Rok vydání:	2009
Předmět:	Diffraction Chemistry Ion chromatography Analytical chemistry chemistry.chemical_element Electron law.invention Ion Field emission microscopy symbols.namesake law Chlorine symbols Physical and Theoretical Chemistry Electron paramagnetic resonance Raman spectroscopy
Zdroj:	Chinese Journal of Chemical Physics. 22:417-422
ISSN:	2327-2244 1674-0068
DOI:	10.1088/1674-0068/22/04/417-422
Popis:	A storage and emission functional material of [Ca24Al28O64]4+(Cl)3.80(O2)0.10 (C12A7-Cl), was prepared by the solid-state reactions of CaCO3, -Al2O3, and CaCl2 in Cl2/Ar mixture atmosphere. The anionic species stored in the C12A7-Cl material were dominated by Cl, about (2.210.24) 1021 cm3, accompanied by a small amount of O2, O, and O2, measured via ion chromatography, electron paramagnetic resonance, and raman spectra measurements. These results also corroborate identification of time-of-flight mass spectroscopythe anionic species emitted from the C12A7-Cl surface were dominated by the Cl (about 90%) together with a small amount of O and electrons. The structure and morphological alterations of the material were investigated via X-ray diffraction and field emission scanning electron microscope, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a6dc44e805b00fd4089f35bb930cff9f https://doi.org/10.1088/1674-0068/22/04/417-422 Zobrazit plný text záznamu