Autor: A. L. Fal'kovskaya, L. N. Bykova
Rok vydání: 2001
Předmět:
Zdroj: Journal of Analytical Chemistry. 56:281-283
ISSN: 1061-9348
DOI: 10.1023/a:1009466825666
Popis: The effect of dye concentrations in solutions on the potential of a copper-selective electrode with a chalcogenide membrane was studied. It was found that the electrode potential depends on the dye concentration in solutions containing no copper ions. Conventional selectivity coefficients of the electrode with respect to dye anions were determined. The selectivity coefficients ambiguously changed with the dye nature and their concentration in solutions. The use of the calibration graph method without taking into account the composition of the test solution gave rise to great errors in the results of determinations.
Databáze: OpenAIRE