Temperature dependence of the reaction nitrogen trioxide + nitrogen dioxide .fwdarw. nitric oxide + nitrogen dioxide + oxygen in the range from 296 to 332 K
| Autor: | B. E. R. Olsson, E. Ljungstroem, J. Davidsson, I. Waengberg |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
Arrhenius equation
Reaction mechanism Infrared Inorganic chemistry General Engineering Analytical chemistry chemistry.chemical_element Concentration ratio Chemical reaction Oxygen chemistry.chemical_compound symbols.namesake Reaction rate constant chemistry symbols Nitrogen dioxide Physical and Theoretical Chemistry |
| Zdroj: | The Journal of Physical Chemistry. 96:7640-7645 |
| ISSN: | 1541-5740 0022-3654 |
| DOI: | 10.1021/j100198a029 |
| Popis: | The reaction NO{sub 3} + NO{sub 2} {yields} NO + NO{sub 2} + O{sub 2} is used to determine the temperature dependence of the [NO]/[NO{sub 2}] ratio in N{sub 2}O{sub 5}/NO{sub 2}/N{sub 2} gas mixtures. The [NO]/[NO{sub 2}] rate coefficients equal k{sub 1}/k{sub 2}, which equals 3.3 x 10{sup -3} exp (-1598/T). From this experiment, the calculated value of k{sub 1} is in the low end of the determinations reported in available literature. |
| Databáze: | OpenAIRE |
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