Living poly(α-methylstyrene) near the polymerization line. 1. Mass density and polymerization line for solutions in tetrahydrofuran
| Autor: | S. C. Greer, K. M. Zheng |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Chemistry Organic Chemistry Solution polymerization Polymer Inorganic Chemistry Solvent Colloid chemistry.chemical_compound Anionic addition polymerization Polymerization Polymer chemistry Materials Chemistry Physical chemistry Relative density Tetrahydrofuran |
| Zdroj: | Macromolecules. 25:6128-6136 |
| ISSN: | 1520-5835 0024-9297 |
| Popis: | The mass density, ρ, of solutions of living poly(α-methylstyrene) in THF was measured as a function of temperature, T, near the polymerization temperatures, T p and the results are compared to two models of equilibrium polymerization as a second-order phase transition: the n→0 magnet model (Kennedy, S. J.; Wheeler, J. J. Caem. Pays. 1983, 78, 1523) and the mean-field model (Tobolsky, A. V.; Eisenberg, A. J. Colloid Sci. 17, 49) as applied to a living polymer in a solvent |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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