Synthese, Struktur von 3-(N,N-dimethylamino) propyl- und 2-(Dimethylaminomethyl)ferrocenyl-Derivaten des Goldes und Platins

Autor:	Klaus Jacob, Kurt Merzweiler, Frank Voigt, Claus Pietzsch
Rok vydání:	1997
Předmět:	Inorganic Chemistry Chemistry Stereochemistry Organic Chemistry Mössbauer spectroscopy Materials Chemistry chemistry.chemical_element Crystal structure Physical and Theoretical Chemistry Platinum Biochemistry Medicinal chemistry
Zdroj:	Journal of Organometallic Chemistry. :421-433
ISSN:	0022-328X
Popis:	[3-(N,N-dimethyIaminopropyl]-lithium (DMAP)Li (I) reacts with chloro(triphenylphosphane)-gol(I) ClAu · P(C6H6)3 to form monometallic organo gold(I)-derivate (DMAP)Au · P(C6H5)3 (1) respectively with [2-(dimethylaminomethyl)ferrocenyl]-lithium (FcN)Li (II) to form a heterobimetallic organo gold(1)-compound (FcN)Au · P(C6H5)3 (2). Reactions of the gold(I)-compIexes ClAu · P(C6H4F-p)3, ClAu · P(C6H4F-m)3 and ClAu · P(C6F5)3 with II lead to the formation of (FcN)Au · P(C6H4F-p)3 (3), (FcN)Au · P(C6H4F-m)3 (4), respectively [FeNAu]2 (5). The platinum(II)-derivatives PtCl2 and cis-Cl2Pt[P(C6H5)3]2 react with II to the heterobimetallic platin organika (FcN)2Pt (6) and (FcN)PtCl · P(C6H5)3 (7). A more detailed characterization of the organo derivatives 1–7 was carried out by elementary analyses, mass-. NMR- and Mossbauer spectroscopy as well as by X-ray crystal structure analyses referring to 2, 5, 6.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a4e1582e1a0e348eb8917069fc95e82e https://doi.org/10.1016/s0022-328x(97)00364-1 Zobrazit plný text záznamu Full Text from ScienceDirect