Temperature Dependence of Mineral Solubility in Water. Part 2. Alkaline and Alkaline Earth Bromides
| Autor: | Boris S. Krumgalz |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Alkaline earth metal
Mineral Aqueous solution Phase equilibrium Inorganic chemistry General Physics and Astronomy Ionic bonding Thermodynamics 02 engineering and technology General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound 020401 chemical engineering chemistry Bromide 0204 chemical engineering Physical and Theoretical Chemistry Solubility Independent data |
| Zdroj: | Journal of Physical and Chemical Reference Data. 47:013101 |
| ISSN: | 1529-7845 0047-2689 |
| DOI: | 10.1063/1.5010290 |
| Popis: | Databases of alkaline and alkaline earth bromide solubilities in water at various temperatures were created using experimental data from publications over about the last two centuries. Statistical critical evaluation of the created databases was produced since there were enough independent data sources to justify such evaluation. The reliable experimental data were adequately described by polynomial expressions over various temperature ranges. Using the Pitzer approach for ionic activity and osmotic coefficients, the thermodynamic solubility products for the discussed bromide minerals have been calculated at various temperature intervals and also represented by polynomial expressions. |
| Databáze: | OpenAIRE |
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