Conductive Polymeric Porphyrins - Characterization And Application For Amperometric Sensors

Autor:	Leszek Czuchajowski, J.R. Fish, Tadeusz Malinski, F. Bailey, Janet E. Bennett
Rok vydání:	2005
Předmět:	Nickel Materials science X-ray photoelectron spectroscopy chemistry Polymerization Inorganic chemistry Electrode chemistry.chemical_element Platinum Spectroscopy Amperometry Dielectric spectroscopy
Zdroj:	[1990] Proceedings of the Twelfth Annual International Conference of the IEEE Engineering in Medicine and Biology Society.
DOI:	10.1109/iembs.1990.691965
Popis:	Highly conductive films have been obtained by oxidative polymerization of tetrakis (p-diethylaminop henyl ) porphyrins (p-Et2N)TPP and tetrakis(3-methoxy-4-hydroxyphenyl) porphyrins (TMHPP) with Fe, Pd, Cu, Ru, Ni, CO as central metals. These films were characterized by using vol tammet ry , ac impedance , UV-vi s i bl e spectroscopy, electron microscopy and x-ray photoelectron spectroscopy. Polymeric CuTMHPP produces a significant photosensitizati on effect and polymeric NiTMHPP can be efficiently demetallated and used as a microsensor for detection of nickel in single biological cells.
Databáze:	OpenAIRE
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