Structural aspects of metal–amide complexes
| Autor: | O. Clement, B. M. Rapko, Benjamin P. Hay |
|---|---|
| Rok vydání: | 1998 |
| Předmět: |
chemistry.chemical_classification
Physics::Biological Physics Quantitative Biology::Biomolecules Denticity Ligand Nanotechnology Crystal structure Coordination complex Inorganic Chemistry Bond length Metal Crystallography chemistry.chemical_compound Molecular geometry chemistry Amide visual_art Materials Chemistry visual_art.visual_art_medium Physics::Chemical Physics Physical and Theoretical Chemistry |
| Zdroj: | Coordination Chemistry Reviews. 170:203-243 |
| ISSN: | 0010-8545 |
| Popis: | An exhaustive survey of crystal structure data on simple amides and metal complexes containing monodentate amide ligands has been performed. Statistical analysis of structural features are reported as a function of the degree of alkylation of the amide functional group, the type of metal ion in the amide complex, and the type of binding to the metal ion. Average values are reported for bond lengths, bond angles, and torsional angles. Orientational preferences of the coordinated amide ligand are discussed in terms of M–O–C bond angles and M–O–C–N torsion angles. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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