| Popis: |
N-(α-amino-alkyl)-benzotriazole, a derivative of Benzotriazole (BTZ), was synthesized via a Mannich reaction addition. The chemical characterization shows that when C19H32N4supramolecule is subjected to heating process the covalent bonds of aminal carbon are broken, modifying supramolecule structure, this results in a rearrangement to the structure dodecan ammonium-1-benzotriazol-1-ate, [BTZ- amine12+].Quantum chemical calculations based on DFT method were performed on the C19H32N4 molecule. The results show that in a derivative of BTZ exists a weak bond where its break may occur. |
