The preparation and coordination chemistry of phosphorus_sulfur donor ligands

Autor:	Nigel Wheatley, Jonathan R. Dilworth
Rok vydání:	2000
Předmět:	chemistry.chemical_classification Sulfide Stereochemistry Homogeneous catalysis Bite angle Medicinal chemistry Coordination complex Inorganic Chemistry chemistry.chemical_compound Deprotonation Thioether chemistry Materials Chemistry Thiol Physical and Theoretical Chemistry Phosphine
Zdroj:	Coordination Chemistry Reviews. 199:89-158
ISSN:	0010-8545
DOI:	10.1016/s0010-8545(99)00185-x
Popis:	This article describes the synthesis and coordination chemistry of five broad types of ligands containing both phosphorus and sulfur donor centres, reviewing the literature up to the end of 1997. Phosphinothiolate ligands combine a phosphine centre with a thiol functionality (usually deprotonated on coordination); phosphinothioether ligands are similar in overall appearance, but contain a thioether group in place of the thiol functionality. Phosphinothioformamides (of general formula R 2 PC(S)NHR′) and phosphinodithioformates (of general formula R 2 PCS 2 − ) belong to the larger class of hetero-allylic ligands, being the phosphorus equivalents of thioureas and dithiocarbamates respectively. Finally, diphosphine monosulfides are related to the well-known diphosphine ligands (e.g. dppe) by the oxidation of one of the two phosphorus(III) centres to a phosphine sulfide. The review contains 340 references and 18 endnotes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9e1b6dc8b67d9069e98085977c375cce https://doi.org/10.1016/s0010-8545(99)00185-x Zobrazit plný text záznamu Full Text from ScienceDirect