Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach
| Autor: | Manoj K. Kesharwani, Janis V. Musso, Matthias Bauer, Joris van Slageren, Mathis J. Benedikter, Johannes Kästner, Michael R. Buchmeiser, Felix Fischer, K. Leonard Sterz, Felix Ziegler, Bernd Plietker, Michal Nowakowski, Mario Winkler, Wolfgang Frey, Iris Elser |
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| Rok vydání: | 2020 |
| Předmět: |
X-ray absorption spectroscopy
Materials science 010405 organic chemistry Cationic polymerization Charge density chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Metal chemistry.chemical_compound Crystallography Delocalized electron chemistry Molybdenum visual_art visual_art.visual_art_medium Carbene |
| Zdroj: | ACS Catalysis. 10:14810-14823 |
| ISSN: | 2155-5435 |
| DOI: | 10.1021/acscatal.0c03978 |
| Popis: | The charge delocalization between the N-heterocyclic carbene (NHC) and the metal in cationic molybdenum imido alkylidene NHC mono(nonafluoro-tert-butoxide) complexes has been studied for different ... |
| Databáze: | OpenAIRE |
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