Synthesis of the C6–C14 Fragment of Euphosalicin

Autor:	Uwe Rinner, Johann Mulzer, Christian Aichinger
Rok vydání:	2015
Předmět:	chemistry.chemical_compound Fragment (logic) Aldol reaction Stereochemistry Chemistry Organic Chemistry Organic chemistry Total synthesis Diterpene
Zdroj:	Synlett. 26:1852-1856
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0034-1380422
Popis:	The synthesis of the C6–C14 fragment of euphosalicin, a highly oxygenated modified jatrophane diterpene, is described. Key steps in the preparation of this versatile intermediate are an Ireland–Claisen rearrangement and a Shibasaki direct asymmetric aldol reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9b0cfdc408f6d68360ba5f693fd015fb https://doi.org/10.1055/s-0034-1380422 Zobrazit plný text záznamu