PPh3-Mediated [3+2] Cycloaddition Reaction between Bis-Substituted Allenoate and N-Tosylaldimines to Construct 2-Pyrrolines

Autor:	Hua Xiao, Xiangwen Kong, Haisheng Qian, Si-Qin Luo, Shilu Fan, Lihua Liu
Rok vydání:	2018
Předmět:	chemistry.chemical_classification chemistry.chemical_compound 010405 organic chemistry Chemistry Alkene Organic Chemistry Triphenylphosphine 010402 general chemistry 01 natural sciences Medicinal chemistry Isomerization Cycloaddition 0104 chemical sciences
Zdroj:	Synlett. 29:1244-1248
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0037-1609489
Popis:	A triphenylphosphine-promoted [3+2] cycloaddition of α,γ-bis-substituted allenoates and N-tosylaldimines followed by alkene isomerization was disclosed, affording a series of functionalized 2-pyrroline derivatives in moderate chemical yields with random diastereoselectivities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9a8de859625362069eabf4c0a263950e https://doi.org/10.1055/s-0037-1609489 Zobrazit plný text záznamu