Adamantylazoles: XI. Reaction of 1-phenyltetrazole-5-thione with adamantan-1-ol in strong acids

Autor:	A. V. Logvinov, I. N. Polyakova, Yu. A. Strelenko, E. L. Golod, Victor V. Saraev
Rok vydání:	2007
Předmět:	chemistry.chemical_compound Hydrolysis chemistry Strong acids Hydrogen Sulfate Mesoionic Organic chemistry Sulfuric acid General Chemistry
Zdroj:	Russian Journal of General Chemistry. 77:2186-2191
ISSN:	1608-3350 1070-3632
Popis:	The reaction of 1-phenyltetrazole-5-thione with adamantan-1-ol in sulfuric acid gave 3-(1-adamantyl)-1-phenyltetrazole-5-thione having a mesoionic structure, 5-(1-adamantylsulfanyl)-1-phenyltetrazole, and 3-(1-adamantyl)-5-(1-adamantylsulfanyl)-1-phenyltetrazolium hydrogen sulfate. Hydrolysis of 5-(1-adamantylsulfanyl)-1-phenyltetrazole led to the formation of 1-phenyltetrazol-5-one. The adamantylation process is reversible.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::998e6e25ceb5701a7c0fe4074083c71f https://doi.org/10.1134/s1070363207120171 Zobrazit plný text záznamu Plný text ve formátu PDF