Polyfluorinated oxacalixarenes. Interaction of perfluoro- m -xylene with resorcinol and tetrafluororesorcinol
| Autor: | Yuri V. Gatilov, Vladimir N. Kovtonyuk |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Organic Chemistry Aromaticity Resorcinol 010402 general chemistry m-Xylene 01 natural sciences Biochemistry Medicinal chemistry 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) X-ray crystallography Environmental Chemistry Phenol Organic chemistry Physical and Theoretical Chemistry Benzene |
| Zdroj: | Journal of Fluorine Chemistry. 199:52-59 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/j.jfluchem.2017.04.010 |
| Popis: | Interaction of perfluoro-m-xylene with tetrafluororesorcinol in Et3N-CH3CN system leads to the formation of perfluorinated tetramethyltetraoxacalix[4]arene with a good yield, while the reaction with resorcinol gives a mixture of macrocycles containing 4, 6 or 8 aromatic rings. The intermediate products in these reactions are perfluoro-3-(2,4-dimethylphenoxy)phenol and 1,3-bis(2,4-bistrifluoromethyltrifluorophenoxy)benzene, respectively. The interaction of the latter with tetrafluororesorcinol leads to the formation of tetraoxacalix[4]arene of ABAC type with a good yield. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect