An Oxygen/Chlorine Double-Capped Praseodymium Tetramer Cluster Complex with Thiazole

Autor: Klaus Müller-Buschbaum, Nicole Dannenbauer
Rok vydání: 2013
Předmět:
Zdroj: Zeitschrift für anorganische und allgemeine Chemie. 639:2737-2740
ISSN: 0044-2313
DOI: 10.1002/zaac.201300263
Popis: A tetramer cluster complex of the formula [Pr4Cl10(OH)2(thz)8(H2O)2] was prepared constituted by two edge sharing metal triangles coordinated by thiazole (thz) and chloride ligands bent together by opposing μ3-hydroxide and chloride capping for both triangles. The tetramer is the first thiazole complex of a lanthanide ion and shows a previously unknown symmetric capping mode. It co-crystallizes with an anhydrous dimeric complex of the formula [Pr2Cl6(thz)8] in equal amounts.
Databáze: OpenAIRE
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