Thermally Reversible Dendronized Step-Polymers Based on Sequential Huisgen 1,3-Dipolar Cycloaddition and Diels−Alder 'Click' Reactions

Autor:	Dominic V. McGrath, James R. McElhanon, Nathan W. Polaske
Rok vydání:	2009
Předmět:	chemistry.chemical_classification Polymers and Plastics Organic Chemistry Polymer Retro-Diels–Alder reaction Reversible reaction Cycloaddition Inorganic Chemistry chemistry.chemical_compound Monomer chemistry Polymerization Polymer chemistry 1 3-Dipolar cycloaddition Materials Chemistry Side chain
Zdroj:	Macromolecules. 43:1270-1276
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma902180r
Popis:	Thermally labile dendronized AA−BB step polymers are described. First through third generation dendritic bisfuran monomers 6a−6c were prepared in part by the Cu(I)-catalyzed azide−alkyne Huisgen 1,3-dipolar cycloaddition reaction and in turn polymerized by the reversible furan−maleimide Diels−Alder reaction. The Diels−Alder reaction conditions were optimized through end-capping studies with N-phenylmaleimide (7). Dendronized step polymers 10a−10c were then formed from reaction with bismaleimide 9 and their assembly, disassembly, and reassembly behavior studied by GPC.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::983ca43ea7df23074aee3683d5da6079 https://doi.org/10.1021/ma902180r Zobrazit plný text záznamu