Silica single-layer inverse opal films: large-area crack-free fabrication and the regulation of transmittance in the visible region
| Autor: | Jian-feng Wang, Yahia Djaoued, Wu Zhe, Jacques Robichaud, Shali Li, Dan Wang, Hua Li |
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| Rok vydání: | 2019 |
| Předmět: |
Fabrication
Yield (engineering) Materials science 02 engineering and technology General Chemistry Substrate (electronics) 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences law.invention chemistry.chemical_compound chemistry law Materials Chemistry Transmittance Calcination SPHERES Polystyrene Composite material 0210 nano-technology Porosity |
| Zdroj: | Journal of Materials Chemistry C. 7:2978-2986 |
| ISSN: | 2050-7534 2050-7526 |
| Popis: | Crack-free large-area SiO2 single-layer inverse opal (IO) films, which possess typical circular holes on their surface similar to an “inverse moth's eye” structure, were designed based on the “dynamic hard-template infiltration strategy” by using a wide range of sizes of sacrificial polystyrene (PS) sphere templates, ranging from 220 to 930 nm. According to this strategy, a dynamic opal single-layer film of PS spheres is firstly self-assembled on the surface of water, followed by the infiltration of SiO2 precursor sol from underneath into the voids of the PS opal template. The obtained floating SiO2/PS opal composite film is deposited on high alumina silicate glass substrates, followed by calcination at 680 °C to yield single-layer SiO2 IO films with various pore sizes presenting a surface configuration similar to an inverse moth's eye structure. The effects of the porous structure on transmittance in the visible region are investigated. The pore depth, pore wall thickness and pore size concurrently play important roles in transmittance. It has been found that the transmittance increases as the opal period decreases and the intersection point between the transmittance spectra of the single-layer SiO2 IO films and that of the bare substrate red shifts as the pore size increases. To our knowledge, this is the first time that the fabrication of silica single-layer IO films having an inverse moth's eye structure and the relationship between their porous structure and optical properties in the visible region have been reported. |
| Databáze: | OpenAIRE |
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