Synthesis of biorenewable and water-degradable polylactam esters from itaconic acid

Autor:	Stephen A. Miller, Hsiao-Li Chen, Chu-Chieh Lin, Pengxu Qi, Ha Thi Hoang Nguyen
Rok vydání:	2016
Předmět:	010405 organic chemistry 010402 general chemistry 01 natural sciences Pollution 0104 chemical sciences Polyester chemistry.chemical_compound Monomer Ethanolamine Polylactic acid chemistry Polymer chemistry Lactam Copolymer Environmental Chemistry Organic chemistry Fermentation Itaconic acid
Zdroj:	Green Chemistry. 18:4170-4175
ISSN:	1463-9270 1463-9262
Popis:	Itaconic acid, a naturally occurring compound mass-produced via fermentation of glucose, was reacted with ethanolamine or ethylene diamine to afford hydroxy-acid or diacid monomers containing the 2-pyrrolidone lactam. Homopolymerization or copolymerization with diols, respectively, yielded polylactam esters with higher glass transition temperatures and faster hydrolytic degradation compared to the commercial polyester polylactic acid (PLA).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::96bed4a1d5565ca0bc02c36286a81341 https://doi.org/10.1039/c6gc01081d Zobrazit plný text záznamu