CO2 adsorption under humid conditions: Self-regulated water content in CAU-10
| Autor: | Adriana Tejeda-Cruz, Eduardo González-Zamora, Ilich A. Ibarra, Valeria B. López-Cervantes, Tamara Jurado-Vázquez, Elí Sánchez-González |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Chemistry
02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Co2 adsorption 01 natural sciences 0104 chemical sciences Inorganic Chemistry Chemical engineering Materials Chemistry Anhydrous Relative humidity Physical and Theoretical Chemistry 0210 nano-technology Water content |
| Zdroj: | Polyhedron. 155:163-169 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/j.poly.2018.08.043 |
| Popis: | The CO2 capture properties of CAU-10 were investigated at different relative humidity conditions. The total CO2 capture increased 1.3-fold from 5.4 wt% under anhydrous conditions to 7.3 wt% at 5% RH and 303 K. The hydrophobicity of the pore provides to the material CAU-10 a ‘self-regulated’ water content, which promoted the enhancement of the CO2 uptake in the low relative humidity domain (3–20% HR), resulting in a ‘constant’ uptake in this whole range. Adsorption–desorption cycles experiments on a hydrated sample, confirmed the retention of the CO2 uptake capacity under humid conditions. CAU-10 showed to be a promising material for CO2 capture under industrial relevant conditions. |
| Databáze: | OpenAIRE |
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