An atom-economical protocol for direct conversion of Baylis–Hillman alcohols to β-chloro aldehydes in water
| Autor: | Vaidya Jayathirtha Rao, Sai Prathima Parvathaneni, Raktani Bikshapathi |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Green chemistry 010405 organic chemistry Sodium Salt (chemistry) chemistry.chemical_element 010402 general chemistry 01 natural sciences Pollution 0104 chemical sciences chemistry.chemical_compound chemistry Metal free Functional group Halogen Atom Environmental Chemistry Organic chemistry |
| Zdroj: | Green Chemistry. 19:4446-4450 |
| ISSN: | 1463-9270 1463-9262 |
| Popis: | This paper describes an atom-economical strategy for the direct conversion of Baylis–Hillman alcohols to β-chloro aldehydes under metal free conditions with excellent functional group tolerance. The use of stable-nontoxic Oxone as a terminal oxidant along with an inexpensive salt (sodium chloride) as a halogen source and water as the reaction medium makes this chemical synthetic process more viable and environmentally benign contributing towards green chemistry. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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