Carboxylate Groups: Deprotonation of Carboxylic Acids and Formation of Coordination Networks

Autor:	Hugo Ascolani, J. E. Gayone, Magalí Lingenfelder, J. D. Fuhr
Rok vydání:	2018
Předmět:	Activation barrier Hydrogen bond Supramolecular chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Deprotonation chemistry Polymer chemistry Carboxylate 0210 nano-technology
DOI:	10.1016/b978-0-12-409547-2.13022-7
Popis:	Carboxylic acids are prototypical building units for the creation of two-dimensional supramolecular architectures on surfaces. The formation of double (dihapto) hydrogen bonds is a common binding geometry of COOH functional groups. On surfaces, however, carboxylates and coordination bonds could also be formed due to the lowering of the activation barrier toward deprotonation of the carboxylic groups. This capacity of forming metal–ligand coordination bonds paved the road toward the creation of a wide variety of surface-confined metal–organic networks. This article is focused on the deprotonation phenomenon in connection with the generation of these types of supramolecular networks under ultra high vacuum conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::92246356af86b5366de3b8e23e3094e7 https://doi.org/10.1016/b978-0-12-409547-2.13022-7 Zobrazit plný text záznamu