Mechanism of DNA cleavage due to green cobalt(III)-bleomycin hydroperoxide irradiated by visible light

Autor: Yuzo Nishida, Satoshi Nishino, Mami Kunita
Rok vydání: 1999
Předmět:
Zdroj: Inorganic Chemistry Communications. 2:156-157
ISSN: 1387-7003
DOI: 10.1016/s1387-7003(99)00036-2
Popis: The origin of the DNA cleavage reaction due to green cobalt(III)-bleomycin hydroperoxide irradiated by light (366 nm) was developed; the importance of the activation of the peroxide ion by transferring an electron from the occupied orbital to the σ * -orbital of the peroxide ion was pointed out.
Databáze: OpenAIRE