Tubular reactor synthesis of styrene–methacrylate copolymers in solution with supercritical carbon dioxide
| Autor: | Michael Buback, Durga Prasad Saggu, Sabine Beuermann, Michael Jürgens, Moritz Gadermann |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
Glycidyl methacrylate
Materials science Supercritical carbon dioxide General Chemical Engineering Analytical chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Methacrylate 7. Clean energy 01 natural sciences 6. Clean water Supercritical fluid 0104 chemical sciences Styrene chemistry.chemical_compound chemistry Chemical engineering Polymerization Copolymer Physical and Theoretical Chemistry Methyl methacrylate 0210 nano-technology |
| Zdroj: | The Journal of Supercritical Fluids. 39:246-252 |
| ISSN: | 0896-8446 |
| DOI: | 10.1016/j.supflu.2006.01.001 |
| Popis: | Terpolymerizations of styrene, methyl methacrylate, and glycidyl methacrylate in solution with supercritical CO2 were carried out in a tubular reactor up to almost complete monomer conversion. The residence time behavior of the set-up was investigated by injecting a tracer pulse and measuring the tracer concentration at the reactor exit via in-line FT-near infrared (NIR) spectroscopy. Molecular weight control during polymerization was achieved either by initiator concentration or by the addition of a catalytic chain-transfer agent. Number average molecular weights were adjusted to about 2500 g mol−1 to yield products which are suitable components for powder coating applications. |
| Databáze: | OpenAIRE |
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