Magnetic Phase Diagrams of Tm2Fe19-xMnx and Tm2Fe17+δ Systems

Autor: I. F. Berger, Galina M. Makarova, Alexandr M. Gabay, A.S. Volegov, V. I. Voronin, A. G. Kuchin, Sergey Platonov
Rok vydání: 2014
Předmět:
Zdroj: Solid State Phenomena. 215:123-126
ISSN: 1662-9779
DOI: 10.4028/www.scientific.net/ssp.215.123
Popis: The Tm2Fe19-xMnx (x = 0 - 1.5) and Tm2Fe16, Tm2Fe17, Tm2Fe18, Tm2Fe19 intermetallic compounds were synthesized and their magnetic and structural properties were studied. Magnetic measurements, X-ray and neutron diffraction investigations were used. The compounds crystallize in a disordered variant of the hexagonal Th2Ni17-type structure. The lattice parameters a, c increases in the Tm2Fe19-xMnx system, whereas c decreases and a increases in the Tm2Fe19 - Tm2Fe16 system as Fe content decreases. The temperatures of ferromagnetic ordering and spin-reorientation increase as Fe content decreases in these systems. Apparently, the decrease of occupation of defected dumbbell Fe (4e) site causes these regularities.
Databáze: OpenAIRE